Sampathkumaran, E. V. ; Perscheid, B. ; Krone, W. ; Kaindl, G. (1985) Valence state of Eu in EuPd2P2 Journal of Magnetism and Magnetic Materials, 47-48 . pp. 407-409. ISSN 0304-8853
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/030488...
Related URL: http://dx.doi.org/10.1016/0304-8853(85)90452-4
Abstract
EuPd2P2 has been classified as mixed-valent from its lattice volume anomaly, while our Mössbauer isomer-shifts and magnetic measurements suggest a divalent-4f7 state. The Eu-LIII-edge X-ray absorption spectrum, however, exhibits a double-peaked structure typical for mixed-valent materials. Various reasons for this apparent discrepancy are discussed including the possible existence of a partly extended 4f radius.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 47282 |
| Deposited On: | 08 Jul 2011 12:57 |
| Last Modified: | 08 Jul 2011 12:57 |
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