X-ray-photoemission-spectroscopy and bremsstrahlung-isochromat-spectroscopy study of the (Y,U)B4 system

Sarma, D. D. ; Krummacher, S. ; Wallash, A. ; Crow, J. E. (1986) X-ray-photoemission-spectroscopy and bremsstrahlung-isochromat-spectroscopy study of the (Y,U)B4 system Physical Review B: Condensed Matter and Materials Physics, 34 (6). pp. 3737-3740. ISSN 1098-0121

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Official URL: http://prb.aps.org/abstract/PRB/v34/i6/p3737_1

Related URL: http://dx.doi.org/10.1103/PhysRevB.34.3737

Abstract

Using x-ray-photoelectron spectroscopy and bremsstrahlung-isochromat spectroscopy (BIS), we have studied the UxY1−xB4 system which shows a magnetic-nonmagnetic transition at x=0.6. Contrary to the conclusions from previous magnetic measurements, we find that the U 5f exhibit itinerant nature for all values of x primarily via hybridization with B s, p states. Evidence of increasing correlation effects with decreasing x is found in the BIS spectra. This is suggested to be responsible for the observed magnetic property.

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