Gehlawat, J. K. ; Sharma, M. M. (1971) Kinetics of absorption of isobutylene in acetic acid Journal of Applied Chemistry and Biotechnology, 21 (5). pp. 141-143. ISSN 0375-9210
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/jctb.50...
Related URL: http://dx.doi.org/10.1002/jctb.5020210506
Abstract
The kinetics of absorption of isobutylene in acetic acid in the presence of concentrated sulphuric acid (98 wt.-%) as catalyst, which results in the formation of t-butyl acetate, was studied in a 10-cm i.d. agitated glass reactor. The solubility of isobutylene in acetic acid and t-butyl acetate was determined experimentally. The reaction is relatively slow and the diffusional factors could be completely eliminated. The values of the second-order reaction rate constant were 0.82 and 2.7 cm3 mole-1 sec-1 at 20° and 40°c, respectively.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 46184 |
| Deposited On: | 02 Jul 2011 10:40 |
| Last Modified: | 02 Jul 2011 10:40 |
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