Jhaveri, A. S. ; Sharma, M. M. (1967) Kinetics of absorption of oxygen in aqueous solutions of cuprous chloride Chemical Engineering Science, 22 (1). pp. 1-6. ISSN 0009-2509
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0009-2509(67)80097-6
Abstract
The kinetics of absorption of oxygen in aqueous solutions of cuprous chloride (in acidic and neutral solutions) was studied in a glass stirred cell. The reactions were found to be second order with respect to cuprous chloride and first order with respect to oxygen. The reaction rate constants at 30°C were found to 295 (1/g mole)2 sec-1 for 5 M HCl solution and 334 (1/g mole)2 sec-1 for 3·75 M NaCl solution. The activation energies were to be 8·35 and 5·9 Kcal/mole for the acidic and neutral solutions, respectively. The effect of ionic strength on the rate constant for the acidic solution was also investigated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 46133 |
| Deposited On: | 02 Jul 2011 10:39 |
| Last Modified: | 02 Jul 2011 10:39 |
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