Kinetics of absorption of HCl in terpenes and isoamylene

Bhargava, R. K. ; Sharma, M. M. (1978) Kinetics of absorption of HCl in terpenes and isoamylene Chemical Engineering Science, 33 (5). pp. 525-531. ISSN 0009-2509

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0009-2509(78)80013-X

Abstract

The kinetics of reaction between HCl gas and terpenes ( α-pinene, myrcene, camphene, Δ3-carene) and isoamylene (2-methyl-2-butene) were studied, The reactions of HCl with a-pinene and Δ3-carene were found to be zero order with respect to HCl and second order with respect to the olefin. T The reactions between HCl and myrcene (in the presence of CuCl as a catalyst) and camphene were found to be first order with respect to HCl as well as The absorption of HCl in 2-methyl-2-butene was found to be second order with respect to HCl and first order with respect to 2-methyl-2-butene. The value.

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