Sampathkumaran, E. V. ; Perscheid, B. ; Kaindl, G. (1984) Valence state of Eu and unit-cell volume anomaly in EuPd2P2 Solid State Communications, 51 (9). pp. 701-704. ISSN 0038-1098
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/003810...
Related URL: http://dx.doi.org/10.1016/0038-1098(84)90950-5
Abstract
Mössbauer isomer shift and magnetic susceptibility measurements clearly prove the divalent nature of Eu in EuPd2P2, a new compound recentlu classified as intermediate valent on grounds of its unit-cell volume anomaly. We explain the relatively small positive deviation in unit-cell volume from the systematic trend in trivalent REPd2P2 compounds as a consequence of strong chemical bonding between the divalent Eu ion and the ligands.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 45695 |
| Deposited On: | 29 Jun 2011 03:12 |
| Last Modified: | 29 Jun 2011 03:12 |
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