Ramaswamy, Ramakrishna ; Rabitz, Herschel ; Green, Sheldon (1978) Rotational inelasticity in high-energy H2---H2 collisions Chemical Physics, 28 (3). pp. 319-329. ISSN 0301-0104
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0301-0104(78)80009-3
Abstract
Rotational cross sections for transitions in the H2---H2 system have been calculated for energies up to ≈2.0 eV and for rotor levels up to j = 11 in the effective potential approximation. The cases of para H2-para H2, ortho H2-ortho H2 and ortho H2-para H2 are considered. Correlations and trends in the cross sections have been examined, and it is shown that the high-energy collisions are dominated by coupling effects. The results of this analysis also suggest that the collision process may be profitably viewed as a diffusion of probability among the levels.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 45350 |
| Deposited On: | 28 Jun 2011 04:42 |
| Last Modified: | 28 Jun 2011 04:42 |
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