New results in the theory of barrierless electronic relaxation in solution

Bagchi, Biman (1987) New results in the theory of barrierless electronic relaxation in solution Chemical Physics Letters, 135 (6). pp. 558-564. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(87)85211-9

Abstract

We present two new theoretical results. Firstly, the existing theories of barrierless electronic relaxation are generalized to include an arbitrary initial population distribution on the excited surface. Secondly, a new model for zero-barrier reaction is presented and solved. This new model may be more appropriate for relaxation in triphenylmethane dyes than existing theoretical models.

Item Type:Article
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ID Code:4530
Deposited On:18 Oct 2010 07:35
Last Modified:18 Oct 2010 07:35

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