Bagchi, Biman (1987) Effects of non-equilibrium solvation dynamics on barrierless electronic relaxation in solution Chemical Physics Letters, 135 (6). pp. 553-557. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(87)85210-7
Abstract
The effects of non-equilibrium solvation dynamics on zero-barrier photoisomerization reactions are studied theoretically. A theory based on general considerations is presented. A two-state model for the time dependence of the sink function is introduced and solved analytically for the survival probability of the excited state. Several interesting non-equilibrium solvation-induced effects which may be experimentally observable are predicted.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 4527 |
| Deposited On: | 18 Oct 2010 07:35 |
| Last Modified: | 18 Oct 2010 07:35 |
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