Isotope effects on the oscillator strengths of the n→π transitions of acetaldehyde and acetone

Rao, C. N. R. ; Murthy, A. S. N. (1966) Isotope effects on the oscillator strengths of the n→π transitions of acetaldehyde and acetone Proceedings of the Physical Society, 87 (3). p. 771. ISSN 0370-1328

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Official URL: http://iopscience.iop.org/0370-1328/87/3/319

Related URL: http://dx.doi.org/10.1088/0370-1328/87/3/319

Abstract

The oscillator strengths of the vibrationally allowed n → π transitions of acetaldehyde and acetone and their deuterated derivatives are shown to depend mainly on the vibrational frequencies of the mixing modes in the deuterated and undeuterated species. Quantitative agreement is found between the calculated and observed intensity ratios fD/fH.

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