A study of LaCoO3 and related materials by X-ray photoelectron spectroscopy

Thornton, G. ; Orchard, A. F. ; Rao, C. N. R. (1976) A study of LaCoO3 and related materials by X-ray photoelectron spectroscopy Journal of Physics C: Solid State Physics, 9 (10). pp. 1991-1998. ISSN 0022-3719

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Official URL: http://iopscience.iop.org/0022-3719/9/10/018

Related URL: http://dx.doi.org/10.1088/0022-3719/9/10/018

Abstract

X-ray photoelectron spectra show changes in the valence bands accompanying the temperature-dependent semiconductor-metal transition in La2NiO4 and the localized-itinerant electron transitions in LaCoO3 and YCoO3. In La1−xSrxCoO3 the valence band changes with the variable x in a manner reflecting the known changes in electronic properties.

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