N.m.r. and infrared spectroscopic studies of hydrogen bonding in hindered alcohols. An instance of a true hydrogen bonded dimer in an alcohol

Becker, Edwin D. ; Tucker, Edwin E. ; Rao, C. N. R. (1977) N.m.r. and infrared spectroscopic studies of hydrogen bonding in hindered alcohols. An instance of a true hydrogen bonded dimer in an alcohol Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 73 (3). pp. 438-442. ISSN 0300-9238

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1977...

Related URL: http://dx.doi.org/10.1039/F29777300438

Abstract

Hydrogen bonding in the highly hindered alcohol 2,4-dimethyl-3-ethyl-3-pentanol has been studied by proton n.m.r. and infrared spectroscopy. This alcohol associates to form a dimer but no higher hydrogen bonded species; hence the monomer-dimer equilibrium can be studied without interference from competing processes. Spectral and thermodynamic properties for the hydrogen bonding are reported.

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