Effect of lithium ion on the torsional barrier in amides

Gurudath Rao, K. ; Becker, Edwin D. ; Rao, C. N. R. (1977) Effect of lithium ion on the torsional barrier in amides Journal of the Chemical Society, Chemical Communications (10). pp. 350-351. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1977...

Related URL: http://dx.doi.org/10.1039/C39770000350

Abstract

1H N.m.r. studies show that the activation energy for internal rotation in [2H]-NN-dimethylformamide is increased by 3.4 kcal mol−1 on complexation with Li+.

Item Type:Article
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ID Code:44602
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