Bhaskar, K. R. ; Gosavi, R. K. ; Rao, C. N. R. (1966) Spectroscopic studies on n-donor +σ-acceptor systems: alkylthioureas and thiocarbanilides Transactions of the Faraday Society, 62 . pp. 29-38. ISSN 0014-7672
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1966...
Related URL: http://dx.doi.org/10.1039/TF9666200029
Abstract
The donor-acceptor interactions of alkylthioureas and thiocarbanilides with halogens have been investigated in detail employing electronic and infra-red spectroscopy. Various correlations of the spectroscopic and thermodynamic data have been presented. Alkylthioureas are by far the strongest donors known, and give high equilibrium constants (10,000-40,000 1. mole−1) and enthalpies of formation (9-18 kcal mole−1). The perturbation of the various vibrational frequencies due to charge transfer have also been studied. Hydrogen bonding of thioureas with hydroxylic compounds have been reported.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 44597 |
| Deposited On: | 22 Jun 2011 12:00 |
| Last Modified: | 22 Jun 2011 12:00 |
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