Simple linear-chain cobalt phosphates

Choudhury, Amitava ; Natarajan, Srinivasan ; Rao, C. N. R. (2000) Simple linear-chain cobalt phosphates Journal of the Chemical Society, Dalton Transactions (15). pp. 2595-2598. ISSN 0300-9246

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2000...

Related URL: http://dx.doi.org/10.1039/B002653K

Abstract

Two simple one-dimensional cobalt phosphates containing linear chains of corner-shared 4-membered rings have been synthesized hydrothermally by the reaction between amine phosphates and cobalt(II) ions under non-aqueous conditions. The linear chains are held together by hydrogen bond interactions involving the hydrogens of the amine and the framework oxygens. The two cobalt phosphates reported are the first linear chain compounds discovered in the family of open-framework transition metal phosphates.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:44574
Deposited On:22 Jun 2011 12:07
Last Modified:22 Jul 2012 14:51

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