Synthesis and characterization of a three-dimensional open-framework lead(II) carboxyethylphosphonate, Pb3(O2CCH2CH2PO3)2

Ayyappan, S. ; Diaz de Delgado, G. ; Cheetham, A. K. ; Férey, G. ; Rao, C. N. R. (1999) Synthesis and characterization of a three-dimensional open-framework lead(II) carboxyethylphosphonate, Pb3(O2CCH2CH2PO3)2 Journal of the Chemical Society, Dalton Transactions (17). pp. 2905-2907. ISSN 0300-9246

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1999...

Related URL: http://dx.doi.org/10.1039/A905326C

Abstract

The hydrothermal synthesis and single crystal XRD characterization of a three-dimensional open-framework lead(II) carboxyethylphosphonate, Pb3(O2CCH2CH2PO3)2, is described; the structure contains PbO3, PbO4 and PbO5 polyhedra, each with stereochemically active lone pairs of electrons, and exhibits several types of channels.

Item Type:Article
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ID Code:44570
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