The error in thermodynamic predictions as a function of the displacement from equilibrium

Rastogi, R. P. ; Denbigh, K. G. (1958) The error in thermodynamic predictions as a function of the displacement from equilibrium Chemical Engineering Science, 7 (4). pp. 261-264. ISSN 0009-2509

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000925...

Related URL: http://dx.doi.org/10.1016/0009-2509(58)85022-8

Abstract

The paper is concerned with the extent to which a thermodynamic prediction of the effect of temperature or pressure on the yield of a reaction is in error, due to the non-attainment of equilibrium. The magnitude of the error is evaluated as a function of the fractional attainment of equilibrium and is shown to be surprisingly large under conditions such as might be encountered in industrial practice.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:44436
Deposited On:21 Jun 2011 14:37
Last Modified:21 Jun 2011 14:37

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