Rastogi, R. P. ; Husain, M. M. ; Chand, Prem ; Misra, G. P. ; Das, Mukul (2002) Anomalous control mechanism in a B-Z type oscillator involving fructose as organic substrate Chemical Physics Letters, 353 (1-2). pp. 40-48. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00092...
Related URL: http://dx.doi.org/10.1016/S0009-2614(01)01487-7
Abstract
In order to elucidate the mechanism of Ce4++BrO3−+H2SO4+fructose [F] oscillatory reaction which has no apparent bromine removal mechanism, detailed experimental studies have been undertaken to investigate (i) [Br−] at different time intervals during oscillations, (ii) effect of addition of (a) Br− during oscillations, (b) fructose and BrO3− after stoppage of oscillations and (c) tartaric acid [TA], below the lower critical limit of [F] for oscillations. A reaction mechanism has been suggested which involves active participation of free radicals and which also correctly predicts most of the observed oscillatory features.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 44358 |
| Deposited On: | 21 Jun 2011 11:40 |
| Last Modified: | 21 Jun 2011 11:40 |
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