Chakrabarti, N. ; Sathyamurthy, N. ; Gadzuk, J. W. (1998) Photoinduced desorption of molecules from metal surfaces using femtosecond pulses: a model dynamical study Journal of Physical Chemistry A, 102 (23). pp. 4154-4157. ISSN 1089-5639
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/jp980043q
Related URL: http://dx.doi.org/10.1021/jp980043q
Abstract
The influence of a femtosecond laser pulse on an adsorbate molecule-metal surface system is investigated by considering a time-dependent coupling between the ground- and excited-state potential energy curves using the time-dependent quantum mechanical wave packet approach. It is shown that the probability of desorption is strongly dependent on the duration of the coupling and the image-charge attraction and that it increases with increase in vibrational excitation of the metal-adsorbate bond.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 43885 |
| Deposited On: | 17 Jun 2011 08:22 |
| Last Modified: | 17 Jun 2011 08:22 |
Repository Staff Only: item control page
