Bhalla, K. C. ; Sathyamurthy, N. (1989) Isotopic branching: experiment versus theory for He+HD+ collisions Chemical Physics Letters, 160 (4). pp. 437-442. ISSN 0009-2614
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0009-2614(89)87623-7
Abstract
Using an accurate ab initio potential energy surface and three-dimensional quasiclassical trajectory collisions, we have investigated the effect of reagent translation and vibration on the cross section for the two isotopically distinct channels of the exchange reaction He+HD+→HeH+D; HeD++H and also on the isotopic branching ratio. While some aspects of our results are in qualitative agreement with the experimental data, there are some serious discrepancies between theory and experiment for the branching ratio.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 43816 |
| Deposited On: | 16 Jun 2011 11:10 |
| Last Modified: | 16 Jun 2011 11:10 |
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