Padmanabhan, M. ; Joseph, James C. ; Thirumurugan, A. ; Rao, C. N. R. (2008) Maleate–fumarate conversion and other novel aspects of the reaction of a Co(II) maleate with pyridine and bipyridine Dalton Transactions (21). pp. 2809-2811. ISSN 0300-9246
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2008...
Related URL: http://dx.doi.org/10.1039/B718623A
Abstract
Reaction of a molecular Co(II) maleate, [Co(Hmal)2(H2O)4], with pyridine yields a Co(II) fumarate, [Co(fum)(H2O)4], with a chain structure and a chiral pyridylsuccinic acid zwitter ion, -OOC–CH(N+C5H5)–CH2–COOH, in almost quantitative yields, while the reaction of 4,4'-bipyridine (bipy) with the Co(II) maleate, on the other hand, almost quantitatively generates a polylmeric Co(II) maleate, [Co(mal)(bipy)]n·(n/2)H2O along with the adduct of fumaric acid with bipyridine.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 43733 |
| Deposited On: | 15 Jun 2011 06:24 |
| Last Modified: | 15 Jun 2011 06:24 |
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