A bimetallic pillared-layer metal–organic coordination framework with a 3D biporous structure

Maji, Tapas Kumar ; Pal, Suchetan ; Gurunatha, K. L. ; Govindaraj, A. ; Rao, C. N. R. (2009) A bimetallic pillared-layer metal–organic coordination framework with a 3D biporous structure Dalton Transactions (23). pp. 4426-4428. ISSN 0300-9246

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2009...

Related URL: http://dx.doi.org/10.1039/B818498D

Abstract

A novel bimetallic [Mn(II)–Fe(III)] 3D biporous pillared-layer metal–organic coordination framework constructed by a cyanometallate anion ([Fe(CN)6]3−) and an organic linker (4,4'-bipy) is found to exhibit permanent porosity with excellent size selective vapour sorption properties and H2-storage capability.

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