Vaidhyanathan, R. ; Natarajan, Srinivasan ; Rao, C. N. R. (1999) Unusual dual role of the organic amine in an open-framework structure Journal of Materials Chemistry, 9 (11). pp. 2789-2793. ISSN 0959-9428
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1999...
Related URL: http://dx.doi.org/10.1039/A905506A
Abstract
The hydrothermal synthesis and single crystal structure determination of a new open-framework zinc phosphate, [NH3(CH2)3NH3]2[NH3(CH2)3NH2]2[Zn12(OH2)2(PO4)10]·H2O, is reported. Crystal data: monoclinic, space group Pn (no. 7), a=13.092(2), b=14.272(2), c=14.220(1) Å, β= 90.3(2)°, V=2656.9(1) Å3, Z=2, M=1927.6, R=0.04. The structure is made up of tetrahedral linkages between ZnO4, ZnO3N and PO4 moieties forming distinct channels. The structure-directing amine is present in two distinct forms, in the free state and as a ligand to zinc, the two species occurring in distinct channels.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 43716 |
| Deposited On: | 15 Jun 2011 05:54 |
| Last Modified: | 18 May 2016 00:37 |
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