Choudhury, Amitava ; Natarajan, Srinivasan ; Rao, C. N. R. (1999) An open-framework iron phosphate with large voids, exhibiting spin-crossover Chemical Communications (14). pp. 1305-1306. ISSN 1359-7345
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1999...
Related URL: http://dx.doi.org/10.1039/A903683K
Abstract
A novel iron phosphate, [(C4N3H16)(C4N3H15)]5+-[Fe5F4(H2PO4)(HPO4)3(PO4)3]5−·H2O, consisting of a Fe-O/F-Fe network crosslinked by PO4 groups is shown to possess unusually large elliptical voids of 24 T atoms (T=Fe, P) and to exhibit a gradual low- to high-spin transformation.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 43689 |
| Deposited On: | 15 Jun 2011 04:38 |
| Last Modified: | 18 May 2016 00:35 |
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