Sankar, G. ; Vasudevan, S. ; Rao, C. N. R. (1987) An EXAFS study of the cobalt-molybdenum/.gamma.-alumina hydrodesulfurization catalyst Journal of Physical Chemistry, 91 (8). pp. 2011-2015. ISSN 0022-3654
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Official URL: http://pubs.acs.org/doi/abs/10.1021/j100292a002
Related URL: http://dx.doi.org/10.1021/j100292a002
Abstract
While Mo in the Co-Mo/y-A1203 hydrodesulfurization catalyst is present as a sulfidic species similar to MoS2, Co shows two types of coordination, one with six sulfurs (but not a bulk sulfide) and the other with four oxygens. The significance of such species is discussed. In addition to an additive relation of the EXAFS function and the residual spectra, the ratio of amplitude terms of the catalyst and the model system has been employed in the analysis.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 43526 |
Deposited On: | 11 Jun 2011 14:21 |
Last Modified: | 16 Jul 2012 08:58 |
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