Yashonath, S. ; Rao, C. N. R. (1986) Structural changes accompanying the formation of isopentane glass Journal of Physical Chemistry, 90 (12). pp. 2581-2584. ISSN 0022-3654
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Official URL: http://pubs.acs.org/doi/abs/10.1021/j100403a008
Related URL: http://dx.doi.org/10.1021/j100403a008
Abstract
On the basis of a detailed Monte Carlo study, it is found that considerable molecular reorientation occurs on the formation of the glassy state of isopentane. The reorientational contribution to the increase in the intermolecular energy on vitrification is at least 50% and reorientational freezing plays a major role near the glass transition. Annealing affects the structure of the glass by a rearrangement involving molecular reorientation.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 43511 |
| Deposited On: | 11 Jun 2011 14:07 |
| Last Modified: | 07 Oct 2011 18:52 |
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