Vinyl polymerisation. VII. Polymerisation of acrylamide photoinitiated by anthraquinone sulphonates

Santappa, M. ; Anwaruddin, Q. (1968) Vinyl polymerisation. VII. Polymerisation of acrylamide photoinitiated by anthraquinone sulphonates Proceedings of the Indian Academy of Sciences, Section A, 68 (4). pp. 186-194. ISSN 0370-0089

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Official URL: http://www.ias.ac.in/j_archive/proca/68/4/186-194/...

Related URL: http://dx.doi.org/10.1007/BF03049419

Abstract

A systematic study of the kinetics of photo-chemical polymerisation of acrylamide using the system anthraquinone sulphonate-NaCl-HClO4 under deaerated condition in aqueous solution has been done. The determinations of the monomer disappearance (bromometry), the sensitiser disappearance (spectrophotometry) and chainlengths of polymers with respect to light intensity, concentration of monomer, light absorption fraction (ke) of sensitiser, etc., have been carried out. An overall kinetic mechanism is given in the light of experimental results.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
ID Code:43391
Deposited On:11 Jun 2011 10:14
Last Modified:18 May 2016 00:24

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