Devarajan, R. ; Balakrishnan, T. ; Santappa, M. ; Viswanathan, B. (1982) Gamma radiation-induced bulk polymerization of some methyl aryloxymethacrylates Journal of Polymer Science - Polymer Chemistry Edition, 20 (7). pp. 1863-1873. ISSN 0360-6376
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/pol.198...
Related URL: http://dx.doi.org/10.1002/pol.1982.170200718
Abstract
The kinetics of γ-radiation-induced bulk polymerization of methyl phenoxymethacrylate and methyl paracresoxymethacrylate was studied at dose rates of 0.3 and 0.075 Mrad/h and at temperatures of 0 and 30°C. The polymerization was first order with respect to the monomers and the rate of polymerization had a direct dependence on dose rate. The activation energy value for the polymerization of methyl phenoxymethacrylate was 1.2 and 0.7 kcal/mol for methyl paracresoxymethacrylate. The polymerization proceeded predominantly by an ionic mechanism.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 43357 |
| Deposited On: | 11 Jun 2011 08:48 |
| Last Modified: | 11 Jun 2011 08:48 |
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