Elayaperumal, P. ; Balakrishnan, T. ; Santappa, M. (1977) A comparison of the absolute reactivity of monomers, 1. Kinetic study of radical polymerization of acrylamide and methacrylamide, initiated by manganese(III) acetate Die Makromolekulare Chemie, 178 (8). pp. 2271-2273. ISSN 0025-116X
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/macp.19...
Related URL: http://dx.doi.org/10.1002/macp.1977.021780814
Abstract
The kinetics of polymerization of acrylamide (AAM) and methacrylamide (MAM) with manganese(III) acetate as thermal initiator was studied. In the temperature range between 303 and 313 K, the initial rate of polymerization follows the relation: v=k[Monomers] · [Initiator]½. The rate of initiation of the polymerization was determined from the rate of decomposition of manganese(III) acetate. The reactivity of the two monomers under the same conditions was compared.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Huthig & Wepf Verlag, Basel. |
| ID Code: | 43302 |
| Deposited On: | 11 Jun 2011 06:27 |
| Last Modified: | 11 Jun 2011 06:27 |
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