Biswas, Ranjit ; Bagchi, Biman (1997) Ionic mobility in alcohols: from dielectric friction to the solvent-berg model Journal of Chemical Physics, 106 (13). pp. 5587-5598. ISSN 0021-9606
Full text not available from this repository.
Official URL: http://link.aip.org/link/?JCPSA6/106/5587/1
Related URL: http://dx.doi.org/10.1063/1.473581
Abstract
A self-consistent microscopic theory is used to calculate the mobility of rigid univalent ions in methanol, ethanol, and propanol at room temperature. The theoretical predictions are in good agreement with the long-known experimental results. In particular, the theory reproduces the nonmonotonic size dependence of the limiting ionic conductance accurately. The relation between the polar solvation dynamics of an ion and its mobility is clarified. The theory also explains how a dynamical version of the classical solvent-berg model can be recovered for small ions in the limit of slow liquids.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Institute of Physics. |
| ID Code: | 4320 |
| Deposited On: | 18 Oct 2010 08:56 |
| Last Modified: | 10 Jan 2011 05:15 |
Repository Staff Only: item control page
