Ir/Sn dual-reagent catalysis towards highly selective alkylation of arenes and heteroarenes with benzyl alcohols

Roy, Sujit ; Podder, Susmita ; Choudhury, Joyanta (2008) Ir/Sn dual-reagent catalysis towards highly selective alkylation of arenes and heteroarenes with benzyl alcohols Journal of Chemical Sciences, 120 (5). pp. 429-439. ISSN 0253-4134

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Official URL: http://www.ias.ac.in/chemsci/Pdf-Sep2008/429.pdf

Related URL: http://dx.doi.org/10.1007/s12039-008-0068-2

Abstract

A catalytic combination of [Ir(COD)Cl]2SnCl4 efficiently promotes the reactions of arenes and heteroarenes with 1°/2°/3° benzyl alcohols as the alkylating agents to afford the corresponding diarylmethane and triarylmethane derivatives in high yields. The scope and limitation of the reaction with respect to catalyst and substrates variation has been studied in detail.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
Keywords:Organometallic; Bimetallic; Catalysis; Alkylation; Benzyl Alcohol; Iridium, Tin
ID Code:42953
Deposited On:08 Jun 2011 08:29
Last Modified:18 May 2016 00:05

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