Gupta, B. D. ; Roy, Sujit (1986) Homolytic displacement at carbon: first example of α-attack in the allenyl and propargyl cobaloximes Tetrahedron Letters, 27 (40). pp. 4905-4908. ISSN 0040-4039
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4039(00)85094-7
Abstract
The reactions of allenyl and propargyl cobaloximes with organosulphonyl chlorides under anaerobic and photochemical conditions form sulphones by a novel homolytic attack at the α carbon to the metal. Allenyl and propargyl sulphones are formed by regiospecific attack of RSO2 on the α carbon bound to cobalt in 1̲ and 6̲. CH2=C=CH-CoIII(dmgH)2Py (1̲)+RSO2Cl—hν CH2=C=CH-SO2R+ClCoIII(dmgH)2Py. CH≡C-CH2-COIII(dmgH)2Py (6̲)+RSO2Cl—hνCH≡C-CH2-SO2R+ClCoIII(dmgH)2Py.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 42950 |
| Deposited On: | 08 Jun 2011 08:24 |
| Last Modified: | 08 Jun 2011 08:24 |
Repository Staff Only: item control page
