Das, Indira ; Roy, Sujit (1994) Organocobaloxime in organic synthesis: efficient trapping of 5-phenylpent-4-ynyl radical by useful functional groups Journal of Organometallic Chemistry, 464 (2). pp. 233-237. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-328X(94)87279-1
Abstract
5-Phenylpent-4-ynyl cobaloxime, R(CoIII) reacts with the free radical precursors XY [X=CCl3, CCl2CN, PhQ, 2, 4-(NO2)2C6H3-S PhSe; Y=Cl, Br, PhQ; Q=S, Se, Te] under thermal or photochemical conditions to give the corresponding organic product RX or RY, depending on the precursor. A non-chain radical mechanism is invoked to account for the product distribution.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cobaloxime; Radical |
| ID Code: | 42948 |
| Deposited On: | 08 Jun 2011 08:21 |
| Last Modified: | 08 Jun 2011 08:21 |
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