Roy, Ujjal Kanti ; Roy, Sujit (2006) SnCl2 mediated efficient N,N-dialkylation of azides to tertiary-amine via potential stannaimine intermediate Journal of Organometallic Chemistry, 691 (8). pp. 1525-1530. ISSN 0022-328X
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...
Related URL: http://dx.doi.org/10.1016/j.jorganchem.2005.12.017
Abstract
A base free one-pot conversion of azides to N,N-dialkylamine is described. A two-step reaction pathway has been postulated invoking the intermediacy of stannaimine. This new carbon-nitrogen bond formation strategy adds to the repertoire of tin(II) chemistry.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Stannaimine; Sn-N; Tin(II); Tin(IV); Azides; Amine |
| ID Code: | 42934 |
| Deposited On: | 08 Jun 2011 07:29 |
| Last Modified: | 08 Jun 2011 07:29 |
Repository Staff Only: item control page
