Dual-reagent catalysis within Ir-Sn domain: highly selective alkylation of arenes and heteroarenes with aromatic aldehydes

Podder, Susmita ; Choudhury, Joyanta ; Roy, Ujjal Kanti ; Roy, Sujit (2007) Dual-reagent catalysis within Ir-Sn domain: highly selective alkylation of arenes and heteroarenes with aromatic aldehydes Journal of Organic Chemistry, 72 (8). pp. 3100-3103. ISSN 0022-3263

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo062633n

Related URL: http://dx.doi.org/10.1021/jo062633n

Abstract

Reactions of arenes and heteroarenes with aromatic aldehydes proceeded smoothly in the presence of a catalytic combination of [Ir(COD)Cl]2-SnCl4 to afford the corresponding triarylmethane derivatives (TRAMs) in high yields. This 100% TRAM selective transformation is clean and eliminates the use of acid systems.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:42917
Deposited On:08 Jun 2011 06:40
Last Modified:08 Jun 2011 06:40

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