Choudhury, Joyanta ; Pratihar, Sanjay ; Maity, Arnab Kumar ; Roy, Sujit (2009) Reactivity of IrCl(PPh3)3 with diphenylacetylene- a direct route to 1-iridaindene Canadian Journal of Chemistry, 87 (1). pp. 183-187. ISSN 0008-4042
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Official URL: http://www.nrcresearchpress.com/doi/abs/10.1139/v0...
Related URL: http://dx.doi.org/10.1139/v08-119
Abstract
The 1-iridaindene complex, Ir[C8H5(Ph-2)]Cl(PPh3)2 (2), has been prepared from the reaction of IrCl(PPh3)3 with PhC≡CPh by a novel direct cycloiridation reaction. A plausible mechanistic pathway has been suggested involving π-coordination assisted ortho- C-H activation and subsequent alkyne hydroiridation reaction to provide the five-member iridacycle.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to NRC Research Press. |
| Keywords: | Iridium; Diphenylacetylene; C-H Activation; Cyclometallation; Metallacycle |
| ID Code: | 42898 |
| Deposited On: | 08 Jun 2011 06:14 |
| Last Modified: | 08 Jun 2011 06:14 |
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