Mahesh, R. ; Kannan, K. R. ; Rao, C. N. R. (1995) Electrochemical synthesis of ferromagnetic LaMnO3 and metallic NdNiO3 Journal of Solid State Chemistry, 114 (1). pp. 294-296. ISSN 0022-4596
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1006/jssc.1995.1044
Abstract
While NdNiO3−δ prepared ordinarily is highly oxygen-deficient and exhibits a metal-insulator transition at low temperature, it has been possible to prepare nearly metallic NdNiO3−δ (δ=0.05) by electrochemical oxidation. On progressive electrochemical oxidation, orthorhombic, insulating LaMnO3 transforms to a rhombohedral and then to a cubic structure. The last two phases are ferromagnetic and exhibit metal-insulator transitions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 42449 |
| Deposited On: | 02 Jun 2011 14:14 |
| Last Modified: | 02 Jun 2011 14:14 |
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