Sankar, G. ; Thomas, John Meurig ; Varma, Vijay ; Kulkarni, G. U. ; Rao, C. N. R. (1996) An investigation of the first-order spin-state transition in Fe(Phen)2(NCS)2 EXAFS and infrared spectroscopy Chemical Physics Letters, 251 (1-2). pp. 79-83. ISSN 0009-2614
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0009-2614(96)00071-1
Abstract
The structure of Fe(Phen)2(NCS)2 has been examined across the first-order spin-state transition by EXAFS with full multiple scattering analysis. The EXAFS data at 298 K can be satisfactorily assigned to the high-spin state, but the analysis of the low-temperature data at 90 K is not entirely unequivocal, although consistent with the predominant presence of the low-spin state. That some proportion of the high-spin state remains at low temperatures, well below the first-order transition, is clearly evidenced in the infrared spectra, suggesting possible sublattice ordering.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 42325 |
| Deposited On: | 02 Jun 2011 12:06 |
| Last Modified: | 02 Jun 2011 12:06 |
Repository Staff Only: item control page
