Neeraj, S. ; Loiseau, T. ; Rao, C. N. R. ; Cheetham, Anthony K. (2004) Synthesis and structure of [C3N2H5][Cu(H2PO4)2Cl]·H2O with a chain structure: the first example of an organically templated copper (II) phosphate Solid State Sciences, 6 (10). pp. 1169-1173. ISSN 1293-2558
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S12932...
Related URL: http://dx.doi.org/10.1016/j.solidstatesciences.2004.05.007
Abstract
A new one-dimensional copper (II) phosphate, [C3N2H5][Cu(H2PO4)2Cl]·H2O, I, with pseudo-10-membered channels along the b-axis formed by the hydrogen bonded chains, containing imidazolium ions has been synthesized and characterized by single-crystal X-ray diffraction. The compound being the first example of an organically templated copper (II) phosphate, crystallizes in the monoclinic space group P21/n (No. 14) with a=8.9998(14) Å, b=7.0189(11) Å, c=18.986(3) Å; β=102.964(3)°; V=1168.8(3) Å3; Z=4. The copper chlorophosphate chains in I are topologically similar to those observed in fornacite and vauquelinite.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 42319 |
| Deposited On: | 02 Jun 2011 10:34 |
| Last Modified: | 02 Jun 2011 10:34 |
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