Vaidhyanathan, R. ; Natarajan, S. ; Rao, C. N. R. (2002) Hydrogen bonded structures in organic amine oxalates Journal of Molecular Structure, 608 (2-3). pp. 123-133. ISSN 0022-2860
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00222...
Related URL: http://dx.doi.org/10.1016/S0022-2860(01)00944-9
Abstract
Oxalates of n-propylamine, n-butylamine, ethylenediamine, 1,4-butanediamine, piperazine, guanidine and 1,4-diazabicyclo[2,2,2]octane (DABCO) have been synthesized and characterized by single crystal X-ray diffraction and other techniques. The amine oxalates show different types of hydrogen bonded networks, linear hydrogen bonded chains characterizing the oxalates of the first five amines. Guanidinium oxalate has a sheet like structure while DABCO oxalate has dimeric hydrogen bonded rings. Hydrogen bonded structures of these oxalates are discussed in detail, besides relating their thermal stability to the strengths of the networks.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Hydrogen Bonding; Linear Chain Oxalates; Dimeric Oxalates |
| ID Code: | 42227 |
| Deposited On: | 02 Jun 2011 07:39 |
| Last Modified: | 22 Jul 2012 14:55 |
Repository Staff Only: item control page
