A comparative Raman study of the interaction of electron donor and acceptor molecules with graphene prepared by different methods

Subrahmanyam, K. S. ; Voggu, Rakesh ; Govindaraj, A. ; Rao, C. N. R. (2009) A comparative Raman study of the interaction of electron donor and acceptor molecules with graphene prepared by different methods Chemical Physics Letters, 472 (1-3). pp. 96-98. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00092...

Related URL: http://dx.doi.org/10.1016/j.cplett.2009.03.003

Abstract

Interaction of tetrathiafulvalene (TTF) and tetracyanoethylene (TCNE) with few-layer graphene samples prepared by the exfoliation of graphite oxide (EG), conversion of nanodiamond (DG) and arc-evaporation of graphite in hydrogen (HG) has been investigated by Raman spectroscopy to understand the role of the graphene surface. The position and full-width at half maximum of the Raman G-band are affected on interaction with TTF and TCNE and the effect is highest with EG and least with HG. The effect of TTF and TCNE on the 2D-band is also maximum with EG. The magnitude of interaction between the donor/acceptor molecules varies in the same order as the surface areas of the graphenes.

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