Ajayaghosh, Ayyappanpillai ; Arunkumar, Easwaran (2005) 1H NMR spectral evidence for a specific host-guest complexation induced charge localization in squaraine dyes Organic Letters, 7 (15). pp. 3135-3138. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol050612u
Related URL: http://dx.doi.org/10.1021/ol050612u
Abstract
Experimental support is provided for the charge localization in squaraines, a class of fundamentally and technologically important organic dyes, by 1H NMR analysis through a host-guest complexation approach. Specific binding of Ca2+ ions to the squaraine 2 with a podand sidearm resulted in a charge-localized structure 2a with dramatic shifts and resolution of the proton signals when compared to those of 2.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 422 |
Deposited On: | 21 Sep 2010 04:38 |
Last Modified: | 27 Sep 2010 10:20 |
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