Chakraborty, Rupak ; Basu, Manas K. ; Ranu, Brindaban C. (1992) α-Hydroxycyclobutane rearrangement followed by retroaldol cleavage: a novel and powerful technology for the stereocontrolled construction of carbocyclic systems. An easy access to angularly functionalised trans-fused cycloheptanoids Tetrahedron, 48 (40). pp. 8849-8854. ISSN 0040-4020
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)89456-4
Abstract
Acid-catalysed rearrangement of α-hydroxycyclobutane derivatives 7a-7c and 11a-11c followed by retroaldol cleavage and oxidation in a single operation furnish angularly carboxylated trans-fused cycloheptanoid derivatives 9a–9c and 12a–12c in good yields.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 42184 |
| Deposited On: | 02 Jun 2011 06:03 |
| Last Modified: | 02 Jun 2011 06:03 |
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