Ranu, Brindaban C. ; Banerjee, Subhash ; Das, Arijit (2004) Selective reductive cleavage of 2,3-epoxybromides by the InCl3-NaBH4 reagent system Tetrahedron Letters, 45 (46). pp. 8579-8581. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.09.120
Abstract
A combination of sodium borohydride and a catalytic amount of indium(III) chloride in acetonitrile reduces 2,3-epoxybromides to the corresponding allylic alcohols in good yields involving reduction of the bromo moiety followed by selective C-O bond cleavage through a radical process. Several aromatic, cyclic and open-chain bromoepoxides successfully participated in this reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Indium(III) Chloride; Sodium Borohydride; 2,3-epoxybromide; Allylic Alcohol; Reduction |
| ID Code: | 42128 |
| Deposited On: | 02 Jun 2011 04:56 |
| Last Modified: | 02 Jun 2011 04:56 |
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