Efficient synthesis of β-alkyl/arylsulfanyl carbonyl compounds by In-TMSCl-promoted cleavage of dialkyl/diaryl disulfides and subsequent Michael addition

Ranu, Brindaban C. ; Mandal, Tanmay (2007) Efficient synthesis of β-alkyl/arylsulfanyl carbonyl compounds by In-TMSCl-promoted cleavage of dialkyl/diaryl disulfides and subsequent Michael addition Synthetic Communications, 37 (9). pp. 1517-1523. ISSN 0039-7911

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Related URL: http://dx.doi.org/10.1080/00397910701229859

Abstract

A convenient and efficient procedure for the synthesis of β-alkyl/arylsulfanyl carbonyl compounds has been developed by a simple one-pot reaction of dialkyl/diaryl sulfides with α,β-unsaturated aldehydes, ketones, carboxylic esters, and nitriles in presence of indium and trimethylsilyl chloride under sonication.

Item Type:Article
Source:Copyright of this article belongs to Taylor and Francis Group.
Keywords:β-alkylsulfanyl Carbonyl Compound; Dialkyl Disulfide; Indium; Sonication; Trimethylsilyl Chloride
ID Code:42092
Deposited On:02 Jun 2011 03:49
Last Modified:02 Jun 2011 03:49

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