Remarkably selective reduction of the α,β-carbon-carbon double bond in highly activated α,β,γ,δ-unsaturated alkenes by the InCl3-NaBH4 reagent system

Ranu, Brindaban C. ; Samanta, Sampak (2003) Remarkably selective reduction of the α,β-carbon-carbon double bond in highly activated α,β,γ,δ-unsaturated alkenes by the InCl3-NaBH4 reagent system The Journal of Organic Chemistry, 68 (18). pp. 7130-7132. ISSN 0022-3263

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo0347821

Related URL: http://dx.doi.org/10.1021/jo0347821

Abstract

A combination of sodium borohydride and a catalytic amount of indium(III) chloride in acetonitrile reduces exclusively the α,β -carbon-carbon double bond in α ,β ,γ ,δ -unsaturated diaryl ketones, dicarboxylic ester, cyanoester, and dicyano compounds.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:42091
Deposited On:01 Jun 2011 18:14
Last Modified:02 Jun 2011 03:48

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