Ranu, Brindaban C. ; Mandal, Tanmay (2006) Indium(I) iodide promoted cleavage of dialkyl/diaryl disulfides and subsequent anti-Markovnikov addition to styrenes: a new route to linear thioethers Tetrahedron Letters, 47 (38). pp. 6911-6914. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.07.017
Abstract
The reaction of thiolate anions, generated in situ by indium(I) iodide promoted cleavage of dialkyl/diaryl disulfides, with styrenes has been investigated. Thiolate anions add to a variety of styrenes in an anti-Markovnikov manner producing linear thioethers in high yields. This method provides a new route to the synthesis of thioethers.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Thioether; Anti-Markovnikov Addition; Styrene; Dialkyl Disulfide; Indium(I) Iodide; Zinc Chloride |
| ID Code: | 42089 |
| Deposited On: | 02 Jun 2011 03:48 |
| Last Modified: | 02 Jun 2011 03:48 |
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