Ranu, Brindaban C. ; Mandal, Tanmay (2004) Indium(I) iodide-promoted cleavage of diaryl diselenides and disulfides and subsequent condensation with alkyl or acyl halides. One-pot efficient synthesis of diorganyl selenides, sulfides, selenoesters, and thioesters The Journal of Organic Chemistry, 69 (17). pp. 5793-5795. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo0493727
Related URL: http://dx.doi.org/10.1021/jo0493727
Abstract
Diphenyl diselenides and disulfides undergo facile cleavages by indium(I) iodide and the corresponding generated selenate and thiolate anions condense in situ with alkyl or acyl halides present in the reaction mixture. Thus, a simple, efficient, and general procedure has been developed for the synthesis of unsymmetrical diorganyl selenides, sulfides (thioethers), selenoesters, and thioesters by this one-pot reaction at room temperature.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 41700 |
| Deposited On: | 31 May 2011 04:53 |
| Last Modified: | 31 May 2011 04:53 |
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