Ionic liquid-promoted stereoselective synthesis of (Z)-vinyl bromides by [bmIm]OH under organic solvent-free conditions: a green approach

Ranu, Brindaban C. ; Banerjee, Subhash ; Gupta, Jhinuk (2007) Ionic liquid-promoted stereoselective synthesis of (Z)-vinyl bromides by [bmIm]OH under organic solvent-free conditions: a green approach Synthetic Communications, 37 (17). pp. 2869-2876. ISSN 0039-7911

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Related URL: http://dx.doi.org/10.1080/00397910701471386

Abstract

A simple and easily accessible ionic liquid, 1-butyl-3-methylimidazolium hydroxide ([bmIm]OH), has been demonstrated as an efficient promoter and reaction medium for the highly stereoselective synthesis of (Z)-vinyl bromides by the debrominative decraboxylation of dibrominated α,β -unsaturated carboxylic acids in high yields. The reaction does not require either a conventional base or an organic solvent.

Item Type:Article
Source:Copyright of this article belongs to Taylor and Francis Group.
Keywords:Debrominative Decarboxylation; Green Synthesis; Ionic Liquid; (z)-vinyl Bromides
ID Code:41515
Deposited On:30 May 2011 05:17
Last Modified:30 May 2011 05:17

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