Ranu, Brindaban C. ; Banerjee, Subhash ; Gupta, Jhinuk (2007) Ionic liquid-promoted stereoselective synthesis of (Z)-vinyl bromides by [bmIm]OH under organic solvent-free conditions: a green approach Synthetic Communications, 37 (17). pp. 2869-2876. ISSN 0039-7911
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Official URL: http://www.informaworld.com/smpp/content~db=all~co...
Related URL: http://dx.doi.org/10.1080/00397910701471386
Abstract
A simple and easily accessible ionic liquid, 1-butyl-3-methylimidazolium hydroxide ([bmIm]OH), has been demonstrated as an efficient promoter and reaction medium for the highly stereoselective synthesis of (Z)-vinyl bromides by the debrominative decraboxylation of dibrominated α,β -unsaturated carboxylic acids in high yields. The reaction does not require either a conventional base or an organic solvent.
Item Type: | Article |
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Source: | Copyright of this article belongs to Taylor and Francis Group. |
Keywords: | Debrominative Decarboxylation; Green Synthesis; Ionic Liquid; (z)-vinyl Bromides |
ID Code: | 41515 |
Deposited On: | 30 May 2011 05:17 |
Last Modified: | 30 May 2011 05:17 |
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