Potential of metal nanoparticles in organic reactions

Ranu, B. C. ; Chattopadhyay, K. ; Saha, A. ; Adak, L. ; Jana, R. ; Bhadra, S. ; Dey, R. ; Saha, D. (2008) Potential of metal nanoparticles in organic reactions Journal of Physics: Conference Series, 106 (1). 012003_1-012003_6. ISSN 1742-6588

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Official URL: http://iopscience.iop.org/1742-6596/106/1/012003

Related URL: http://dx.doi.org/10.1088/1742-6596/106/1/012003

Abstract

Palladium(0) nanoparticle has been used as efficient catalyst for (a) the stereoselective synthesis of (E)- and (Z)-2-alkene-4-ynoates and -nitriles by a simple reaction of vic-diiodo-(E)-alkenes with acrylic esters and nitriles and (b) for the allylation of active methylene compounds by allylacetate and its derivatives. Copper(0) nanoparticle catalyzes aryl-sulfur bond formation very efficiently. All these reactions are ligand-free.

Item Type:Article
Source:Copyright of this article belongs to Institute of Physics.
ID Code:41455
Deposited On:30 May 2011 05:32
Last Modified:17 May 2016 23:11

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